| Champions League | 11/03 15:40 | - | Andreas Levenko v Diogo Carvalho | W | 2-3 | |
| Champions League | 11/03 13:55 | - | Nandor Ecseki v Diogo Carvalho | L | 3-2 | |
| EM | 06/24 18:20 | 6 | Simon Gauzy v Diogo Carvalho | L | 4-2 | |
| EM | 06/23 16:00 | - | Diogo Carvalho v Marko Jevtovic | W | 3-0 | |
| EM | 06/22 11:55 | - | Andreas Levenko v Diogo Carvalho | L | 3-2 | |
| Spanish Cup | 06/16 11:20 | - | Diogo Carvalho v Viktor Brodd | W | 3-1 | |
| Spanish Cup | 06/16 10:21 | - | Diogo Carvalho v Marc Duran | W | 3-1 | |
| Champions League | 12/15 17:00 | - | Timo Boll v Diogo Carvalho | L | 3-0 | |
| Champions League | 12/15 16:25 | - | Anton Kallberg v Diogo Carvalho | L | 3-0 | |
| Champions League | 12/13 09:00 | - | Simon Belik v Diogo Carvalho | W | 0-3 | |
| Champions League | 12/12 10:00 | - | Diogo Carvalho v Liam Pitchford | L | 1-3 | |
| Champions League | 12/12 09:00 | - | Diogo Carvalho v Jonathan Groth | L | 2-3 | |
| Hungarian Open | 02/18 13:50 | - | Diogo Carvalho v Tiago Apolonia | L | 0-4 | |
| Europe Cup | 02/16 19:32 | - | Diogo Carvalho v Sebastian Loso | W | 3-0 | |
| Portugal Open | 02/14 20:00 | 5 | Emmanuel Lebesson v Diogo Carvalho | L | 4-1 | |
| Portugal Open | 02/14 14:05 | 6 | Diogo Carvalho v Brian Afanador | W | 4-1 | |
| Portugal Open | 02/13 15:20 | - | Diogo Carvalho v David Serdaroglu | W | 4-2 | |
| Portugal Open | 02/12 15:45 | - | Diogo Carvalho v Maciej Kolodziejczyk | W | 4-1 | |
| Europa - Champions League | 12/10 18:00 | - | Ronald Redjep v Diogo Carvalho | W | 0-3 | |
| Europa - Champions League | 12/05 17:30 | - | Diogo Carvalho v Anton Kallberg | L | 0-3 | |
| Europa - Champions League | 10/31 21:10 | - | Shengpeng Fan v Diogo Carvalho | L | 3-1 | |
| Europa - Champions League | 10/31 18:30 | - | Cedric Nuytinck v Diogo Carvalho | L | 3-0 | |
| Europa - Champions League | 10/23 17:00 | - | Diogo Carvalho v Shengpeng Fan | W | 3-2 | |
| Europa - Champions League | 10/18 19:40 | - | Diogo Carvalho v Liang Qiu | W | 3-0 | |
| Europa - Champions League | 10/18 17:40 | - | Diogo Carvalho v Chia-Hung Sun | L | 0-3 | |
| Europa - Champions League | 09/13 17:00 | - | Timo Boll v Diogo Carvalho | W | 1-3 | |
| China Open | 05/28 04:50 | - | Quadri Aruna v Diogo Carvalho | L | 4-0 | |
| Serbia Open | 05/04 11:00 | - | Abdel Kader Salifou v Diogo Carvalho | L | 4-2 | |
| Qatar Open - Kvinder | 03/08 19:45 | - | Diogo Carvalho v Liam Pitchford | L | 1-3 | |
| Tjekkiet - Extraliga | 02/15 14:30 | - | Yukiya Uda v Diogo Carvalho | L | 4-2 |